对苯二甲酸根桥联的铜配合物的合成和性质研究  

Syntheses, Properties of Binuclear Copper(Ⅱ) Compound Bridged by Phthalic Anion

作　　者：尹春玲 杨维春 

机构地区：[1]平顶山师专,河南平顶山467002

出　　处：《平顶山师专学报》2001年第2期51-52,共2页Journal of Pingdingshan Teachers College

摘　　要：合成了两个以对苯二甲酸根为桥的双核铜配合物 通过元素分析确定了配合物的组成 ,并用红外、电导和紫外光谱表征了配合物 。Two novel compounds have been synthesized and characterized by elemental analysis, IR and UV-vis spectra. The temperature dependent-magnetic susceptibilities have been studied in the range 2-300 K, and the exchange integral 2J is found to be -48.6 cm -1 . The result suggests the moderately strong antiferromagnetic exchange interaction between the copper ions.

关 键 词：对苯二甲酸根 铜配合物 螯合配体 反铁磁偶合 桥联配体 结构表征 合成 

分 类 号：O614.121[理学—无机化学]