双—（二烷硫基四硫富瓦烯二硫）金属配合物的合成及性质研究  

Study on Synthesis and Properties of Bis- (bisalkylthio tetrathiafulvalene - dithiolate) Metal Complexes

作　　者：杨更新[1] 迟兴宝[1] 王小刚[1] 王建华[1] 

机构地区：[1]西北大学化学系,

出　　处：《化学学报》2001年第5期751-754,共4页Acta Chimica Sinica

基　　金：陕西省自然科学基金

摘　　要：合成了三种未见文献报道的双-(二烷硫基四硫富瓦烯二硫)金属配合物和三种新的四硫富瓦烯(TTF)桥联的双金属配合物,测定了它们的电导率,讨论了含Ni配合物的电导率优于含Cu,Hg配合物的原因.Three new bis - (bisalkylthio - tetrathiafulvalene - dithiolate) metal complexes and three new bimetal complexes coordinated to TTF were synthesized. Their conductivity was determined. The reasons for the better conductivity of the Ni complexes than that of Cu and Hg were also discussed.

关 键 词：双-(二烷硫基四硫富瓦烯二硫)金属配合物 双金属配合物 合成 电导率 有机导体 铜 镍 汞 

分 类 号：O641.4[理学—物理化学]