STRUCTURE OF [Et_4N]_2[Mo_2(CO)_8(SCH_2C_6H_4CH_2SH)]  

作　　者：黄梁仁 庄伯涛 等 

出　　处：《Chinese Journal of Structural Chemistry》1989年第1期19-22,共4页结构化学（英文）

摘　　要：Mr =1015.05, P21/c, a= 10.912(4), b= 12.088(3), c= 18.807(8) A.β=103.57(3)° ,V= 2411.4 A3, Z = 2, DC = 1.40 g/cm3.λ(MoKα)= 0.71073 A, μ=7.2 cm-1,F(000)=1048.Room temperature, final R=0.069, Rw=0.091. The geometry around the Mo atom is a distorted octahedron. The equatorial Mo-C distances are shorter than the axial ones. The Mo...Mo distance is 3.949A.Mr =1015.05, P21/c, a= 10.912(4), b= 12.088(3), c= 18.807(8) A.β=103.57(3)° ,V= 2411.4 A3, Z = 2, DC = 1.40 g/cm3.λ(MoKα)= 0.71073 A, μ=7.2 cm-1,F(000)=1048.Room temperature, final R=0.069, Rw=0.091. The geometry around the Mo atom is a distorted octahedron. The equatorial Mo-C distances are shorter than the axial ones. The Mo...Mo distance is 3.949A.

关 键 词：四乙基铵 羰基 二元配合物 钼 晶体结构 邻苯二甲硫醇 

分 类 号：O614.612[理学—无机化学] O76[理学—化学]