STRUCTURAL STUDIES OF DICHLORO-(4,7-DIPHENYLPHENANTHBOLINE)DIBUTYLTIN(Ⅳ) ETHANOL SOLVATE,[SnBu_2Cl_2(DPphen)]·C_2H_5OH  

作　　者：胡盛志 黄泽兴 等 

出　　处：《Chinese Journal of Structural Chemistry》1989年第1期36-39,共4页结构化学（英文）

基　　金：Project supported by the NNSF

摘　　要：C34H40N2OCl2Sn,Mr=682.3, triclinic, P1, a = 10.082(1),b= 10.932(1), c=15.666(2) A,α= 79.85(1),β=84.19(1),γ=84.92(1)°;V =1686.5 A3,Z = 2,Dc = 1.344 g.cm-3,μ(MoKα) = 9.5 cm-1, T=294(1)K. The coordination of tin is essentially octahedral, with the nitrogen atoms from bidentate ligand DPphen and cis-chlorine atoms lying in the equatorial plane and the two carbon atoms from trans-butyl groups in the axial positions. The average Sn-N distance of 2.39A happens to be in the shortest limit for this kind of complexes exhibiting antitumor activity.C34H40N2OCl2Sn,Mr=682.3, triclinic, P1, a = 10.082(1),b= 10.932(1), c=15.666(2) A,α= 79.85(1),β=84.19(1),γ=84.92(1)°;V =1686.5 A3,Z = 2,Dc = 1.344 g.cm-3,μ(MoKα) = 9.5 cm-1, T=294(1)K. The coordination of tin is essentially octahedral, with the nitrogen atoms from bidentate ligand DPphen and cis-chlorine atoms lying in the equatorial plane and the two carbon atoms from trans-butyl groups in the axial positions. The average Sn-N distance of 2.39A happens to be in the shortest limit for this kind of complexes exhibiting antitumor activity.

分 类 号：O614.432[理学—无机化学] O76[理学—化学]