CRYSTAL STRUCTURE OF UO_2 (PMBP)_2 (TBPO)(HPMBP=1-Phenyl-3-Methyl-4-Benzoylpyrazolone-5,TBPO=Bu_4PO)  

作　　者：汪明 于志辉 等 

出　　处：《Chinese Journal of Structural Chemistry》1989年第3期173-176,共4页结构化学（英文）

摘　　要：C46H44N4O7PU, Mr = 1033. 89, monoclinic space group C2/c,a= 24. 110(3),b= 16. 879(2),c=27. 751(4) A ,B=96. 69(1),V= 11216. 5A3,Z=8, Dc=1.224 gcm-2, (MoKa) = 0. 71073A,u= 28.123cm-1,F(000) = 511, final R = 0. 052 for 3806 observable reflections. The uranyl ion UO|+ in the title complex forms a distorted pentagonal bipyramidal geometry with five oxygen atoms in the equatorial plane from two PMBP and one TBPO groups.C46H44N4O7PU, Mr = 1033. 89, monoclinic space group C2/c,a= 24. 110(3),b= 16. 879(2),c=27. 751(4) A ,B=96. 69(1),V= 11216. 5A3,Z=8, Dc=1.224 gcm-2, (MoKa) = 0. 71073A,u= 28.123cm-1,F(000) = 511, final R = 0. 052 for 3806 observable reflections. The uranyl ion UO|+ in the title complex forms a distorted pentagonal bipyramidal geometry with five oxygen atoms in the equatorial plane from two PMBP and one TBPO groups.

分 类 号：O614.62[理学—无机化学] O76[理学—化学]