卟啉类化合物的合成——Ⅰ.meso-(羟基苯)卟啉合成的研究  

Synthesis of porphyrins I.Studies on the synthesis of meso-hydroxyphenylporphyrins(THPP)

作　　者：陈德麒[1] 刘恒椽[1] 

机构地区：[1]华东师范大学化学系,上海200062

出　　处：《化学试剂》1991年第3期149-152,共4页Chemical Reagents

基　　金：中国科学院基金

摘　　要：在研究卟啉类各种合成方法的基础上,研究了由羟基苯甲醛和吡咯在丙酸中一步合成羟基苯卟啉的方法。并用此法合成了 T(2-HP)P、T(3-HP)P、T(4-HP)P 和 T(3,4-DHP)P,同时还对 T(3,4-DHP)P 和 T(2-AP)P 等的反应温度、时间、介质作了进一步的研究。Hydroxyphenylporphyrins are a sort of colorreagents with superhigh sensitivity.On the basisof studying different kinds of methods,the directsynthesis of meso-hydroxyphenylporphyrins in onestep has been achieved in this paper.Hence,T-(2-HP)P,T(3-HP)P,T(4-HP)P and T(3,4-DHP)Phave been synthesized.The synthetic methodof T(3,4-DHP)P and the improvement ofsynthesis of T(2-AP)P have also been studied.

关 键 词：卟啉类 合成 羟基苯 卟啉 

分 类 号：TQ421.383[化学工程]