聚 N,N-(β-二茂铁)-二乙基-γ-氨丙基硅氧烷钯催化剂的合成及其加氢活性  

Synthesis and hydrogenation activity of poly-N,N-(β-ferrocenyl)-diethyl-γ-aminopropyl siloxane palladium complex catalyst

作　　者：游江[1] 刘基万[1] 张雪君 罗尚龙 

机构地区：[1]武汉大学化学系,武汉430072

出　　处：《化学试剂》1991年第6期340-342,376,共4页Chemical Reagents

基　　金：国家自然科学基金委员会课题

摘　　要：介绍了4种不同N/Pd摩尔比的聚N,N-(β-二茂铁)-二乙基-γ-氨丙基硅氧烷钯双金属催化剂的合成及其加氢活性,并对其与相应单金属催化剂的加氢活性进行了比较。这类双金属催化剂的加氢活性比相应单金属催化剂的高得多,且其起始吸氢速度随 N/Pd 比的增加而增大。The present investigation is concerned withthe synthesis of the title bimetallic catalyst andthe study on its hydrogenation activity for ole-fines and nitrobenzene compared with the corre-sponding palladium(or iron)monometallicanalogue.The results indicated that the initial hydro-gen absorption rate increased with increasing N/Pd ratio and the hydrogenation activity of thebimetallic catalysts was much higher than thatof the monometallic analogue.

关 键 词：钯催化剂 铁 聚合物 固载 加氢活性 

分 类 号：TQ426.82[化学工程]