棒状薄层色谱/氢火焰离子化检测器法测定重油烃族组成影响因素的探讨  

Investigation on influencing factors in determination of hydrocarbons in heavy oils by thin layer chromatography flame/ionization detector.

作　　者：杨海鹰[1] 顾洁[1] 蔺玉贵[1] 

机构地区：[1]中国石油化工集团公司石油化工科学研究院,北京100083

出　　处：《分析仪器》2001年第2期27-29,共3页Analytical Instrumentation

摘　　要：对应用棒状薄层色谱 /氢火焰离子化检测器 (TLC/FID)测定重油烃族组成 (饱和烃、芳烃、胶质 )时的影响因素作了探讨。研究发现 ,在点样及展开过程中 ,溶剂共挥发可引起样品损失 ;而且 ,由于TLC/FID的火焰温度远低于一般GC条件下FID的火焰温度 ,使不同化合物在FID上的燃烧转化情况有差异 。The influencing factors in the determination of hydrocarbons (saturates, aromatics, resins) in heavy oils by thin layer chromatography/flame ionization detection (TLC/FID) were investigated. It has been found that the solvent co volatization may cause sample loss during the spotting and developing process, and that the quantitative calibration factors can not be used universally. Because the flame temperature of TLC/FLD is much lower than that of GC/FID, the transformation of different compounds in the flame of FID is varied.

关 键 词：棒状薄层色谱 氢火焰离子化检测器 重油烃族组成 定量校正因子 测定 TLC/FID 

分 类 号：O657.7[理学—分析化学]