C_(60)臭氧化生成C_(60)O_n(n=1～5)的研究  

STUDIES ON THE PRODUCT C_(60)O_n (n=15) OF THE OZONIZE OF C_(60)

作　　者：郝策[1] 滕启文[1] 吴师[1] 尚贞锋[1] 李文兰[1] 潘荫明[1] 甘尉棠[1] 唐敖庆[1] 

机构地区：[1]南开大学化学系,天津300071

出　　处：《南开大学学报（自然科学版）》2001年第2期6-12,共7页Acta Scientiarum Naturalium Universitatis Nankaiensis

基　　金：国家自然科学基金!(2 0 0 730 2 2 )

摘　　要：对C60 臭氧化反应的产物C60 On 进行UV vis光谱测定和理论分析 .指认C60 On 异构体高效液相色谱 (HPLC)峰归属的可能结构 ,对HPLC峰的保留时间 (tR)与极性的相关性进行探讨 ,初步设想了反应的局部网络机理 .The electronic spectra of various fullerene oxides C 60 O n(n=1~5) introduced by ozonization have been studied, and the equilibrium structures as well as the electronic spectra have been predicted using semiempirical INDO method in this paper. The HPLC peaks of C 60 O n have been identified, the correlation between the retention times and dipoles of these fullerene oxides has been studied, and the network reaction mechanism has been introduced.

关 键 词：臭氧化 UV-VIS光谱 高效液相色谱 量化计算 碳60 异构体结构 保留时间 

分 类 号：O613.71[理学—无机化学] O641.12[理学—化学]