1,13-二苯基-4,7,10-三氧杂-1,13-二砷杂环十八烷的合成  

Synthesis of 1,13-diphenyl-4,7,10-trioxa-1,13-diarsacyclooctadecane

作　　者：陈新友[1] 汪连生[1] 于伦友[2] 

机构地区：[1]孝感学院化学系,湖北孝感432100 [2]广水市第一中学,湖北广水432700

出　　处：《孝感学院学报》2001年第3期47-49,共3页JOURNAL OF XIAOGAN UNIVERSITY

摘　　要：以苯胂酸为原料通过两步反应合成了中间体 1 ,5-双 (苯胂基 )戊烷 ,用该中间体与四甘醇二氯醚进行环缩合反应合成了砷杂冠醚 1 ,1 3 二苯基 -4 ,7,1 0 -三氧杂 -1 ,1 3 -二砷杂环十八烷。目标物的组成和结构通过IR ,1HNMR ,MS等进行了表征。bis(phenylarsino)pentane was prepared by using of phenylarsonic acid as initial compound over two steps of reactions.A arsa crownether compound 1,3 diphenyl 4,7,10 trioxa 1,13 diarsa cyclooctadecane was synthesized by the cyclocondensation reaction of 1,5 bis(phenylarsino)pentane with ClCH 2(CH 2OCH 2) 3CH 2Cl.The structure of target compound was characterized by IR, 1HNMR and MS.

关 键 词：1 5-双(苯胂基)戊烷 砷杂冠醚 合成 1 13-二苯基-4 7 10-三氧杂-1 13-二砷杂环十八烷 

分 类 号：O623.423[理学—有机化学]