高分子梯度玻璃的研制和表征  

Preparation and characterization of polymer gradient glass

作　　者：顾明冬[1] 李林艳[2] 

机构地区：[1]江苏省盐城卫生学校,江苏盐城224006 [2]北京大学化学与分子工程学院,北京100871

出　　处：《南京化工大学学报》2001年第3期45-48,共4页Journal of Nanjing University of Chemical Technology(Natural Science Edition)

摘　　要：利用溶胶凝胶法制备高分子梯度玻璃前体 ,在这个体系中加入钛酸丁酯 ,形成高分子梯度玻璃。采用X射线散射能谱 (EDAX)、吸收光谱仪、隧道扫描电子显微镜 (SEM)、射线衍射仪 (XRD)对产品进行了表征 ,发现在样品(棒状 )中钛离子浓度由中心向边缘逐渐降低 ,呈梯度分布 ,样品在可见光范围内无明显的吸收峰 ,说明样品有较好的光学透明性 ,材料的颗粒分布均匀 ,粒径的大小为 40～ 6 0nm ,说明其有机相和无机相是均匀混合的 。The glass which has continuous variation of refractive index either in the radial or the axial direction is called gradient glass. This material has been extensively applied in optical and photoelectronic device such as compact photocopies, communication relay systems, medical imaging systems, etc. A new type of polymer gradient glass has been successfully prepared by the sol-gel method in our laboratory. First,poly-dimethylsiloxane(PDMS) was incorporated with tetraethy(ortho)siloxane(TEOS) by sol-gel method to obtain an organic and inorganic hybrid system. Then, Ti(OBu) 4 was added to this system by sol-gel method. Finally, a new type of polymer gradient glass was obtained. This material shows good optical transparency and gradient property. Moreover ,it is superior to the traditional gradient material in hardness and toughness.

关 键 词：溶胶-凝胶法 高分子梯度玻璃 制备 钛酸丁酯 EDAX SEM XRD 光学透明性 表征 

分 类 号：TQ171.7[化学工程—玻璃工业]