草酰胺桥联大环二羰四胺Cu(Ⅱ)-M(Ⅱ)(M=Mn,Ni,Cu,Zn)异双核配合物的合成与表征  

Synthesis and Characteristics of Heterobinuclear Cu(Ⅱ)-M(Ⅱ) (M=Mn,Ni,Cu,Zn) Complexes from New Oxalamide Bridging Macrocyclic Dioxotetraamines Ligand

作　　者：臧双全[1] 陶偌偈[1] 娄本勇[1] 

机构地区：[1]河南大学化学化学化工学院,开封475001

出　　处：《化学研究》2001年第2期18-20,共3页Chemical Research

基　　金：河南省教委自然科学基金项目 (9915 0 0 2 4)

摘　　要：合成了四种新型具有草酰胺桥联大环二羰四胺结构Cu(Ⅱ ) -M(Ⅱ ) (M =Mn ,Ni,Cu ,Zn)的双核配合物 ,并用元素分析 ,红外光谱 ,紫外光谱 ,摩尔电导 ,热重分析 ,室温磁矩等手段对其进行了结构表征 .经研究推定 ,此配合物具有草酰胺桥联结构 ,Cu(Ⅱ )处于平面正方场M(Ⅱ )处于八面体场中 .Cu(Ⅱ)_M(Ⅱ) (M=Mn, Ni, Cu, Zn) heterobinuclear complexes from new oxalamide bridging macrocyclic dioxotetraamines ligand are synthesized. They are characterized by elemental analysis, IR, UV_visible spectra, molar conductivity, thermogravity analysis and room temperature magetic moments. Study shows that there are Cu(Ⅱ)_M(Ⅱ) heterobinuclear complexes with Oxamidgin_bridging structure, Copper(Ⅱ) with a planar environment and M(Ⅱ) with an octahedral environment.The study of room temperature magnet shows that there are weak antiferromagetic interactions between the two metal ions within a molecule.

关 键 词：草酰胺桥联 异双核配合物 反铁磁性 大环二羰四胺 铜 合成 表征 结构 

分 类 号：O614.121[理学—无机化学]