一个新型层状化合物[Ni(C_(10)H_8N_2)_2V_3O_(8.5)]的水热合成与晶体结构  

Hydrothermal Synthesis and Crystal Structure of a Novel Layered Compound [Ni(C_(10)H_8N_2)_2V_3O_(8.5)]

作　　者：栾国有[1] 王恩波[1] 韩正波[1] 李阳光[1] 鹿颖[1] 胡长文[1] 胡宁海[2] 贾恒庆[2] 

机构地区：[1]东北师范大学化学学院,长春130024 [2]长春应用化学研究所,长春130022

出　　处：《高等学校化学学报》2001年第8期1290-1291,共2页Chemical Journal of Chinese Universities

基　　金：国家自然科学基金 (批准号 :2 97710 0 6 )

摘　　要：A novel layered compound, [Ni(C 10 H 8N 2) 2V 3O 8 5 ], was hydrothermally synthesized and structurally characterized by single crystal X ray diffraction. The compound crystallizes in monoclinic system, space group P2 1/c with a =1 551 8(3) nm, b =1 476 1(3) nm, c =1 048 3(2) nm, β=92 02(3)°, V = 2 399 8 (8) nm 3, Z=4, R=0 046 7, wR 2= 0 085 9.A novel layered compound, [Ni(C 10 H 8N 2) 2V 3O 8 5 ], was hydrothermally synthesized and structurally characterized by single crystal X ray diffraction. The compound crystallizes in monoclinic system, space group P2 1/c with a =1 551 8(3) nm, b =1 476 1(3) nm, c =1 048 3(2) nm, β=92 02(3)°, V = 2 399 8 (8) nm 3, Z=4, R=0 046 7, wR 2= 0 085 9.

关 键 词：水热合成 层状化合物 晶体结构 多金属氧酸盐配合物晶体 钒 镍 

分 类 号：O614.511[理学—无机化学] O614.813[理学—化学]