香桂叶油合成胡椒基丁醚  

SYNTHESIS OF PIPERONYL BUTOXIDE FROM CPL OIL

作　　者：蓝文祥[1] 蔡君[2] 巫建国[2] 

机构地区：[1]渝州大学化学系,重庆400033 [2]四川省日用化学工业研究所,重庆400065

出　　处：《化学研究与应用》2001年第3期296-298,共3页Chemical Research and Application

基　　金：重庆科学基金资助攻关项目 !(98- 5 15 6)

摘　　要：In this paper,a route to the synthesize piperonyl butoxide (PB) [51 03 6] from CPL Oil is reported.This environmentally amicable synthesis of piperonyl butoxide involves the hydrogenation of CPL Oil with Raney Ni W 2 as catalyst,the chloromethylation of dihydrosafrole (DHS) [94 58 6],and the etherification of chloromethyldihydrosafrole (CMDHS)[1938 32 5].The Cinnamomum Petrophilum Leaves Oil(CPL Oil) is an essential oil from leaves of a plant of Cinnamomum Petrophilum Nees.Chao.The PB is a synergist for pyrethrin insecticides.Thus,a mixture of 0.982 mol of CMDHS,1.27 moles of butyl carbitol,1.18 moles of NaOH was refluxed for 1.2 houres at 140℃ to give yield 84.4% of PB (purity≥89.5%).The total yield is 81.5% for CPL oil.After the wastewater of etherification was treated,CODCr can be reduced to 12 mg/L,colority can be reduced 46 time,pH can be changed to 8.In this paper,a route to the synthesize piperonyl butoxide (PB) [51 03 6] from CPL Oil is reported.This environmentally amicable synthesis of piperonyl butoxide involves the hydrogenation of CPL Oil with Raney Ni W 2 as catalyst,the chloromethylation of dihydrosafrole (DHS) [94 58 6],and the etherification of chloromethyldihydrosafrole (CMDHS)[1938 32 5].The Cinnamomum Petrophilum Leaves Oil(CPL Oil) is an essential oil from leaves of a plant of Cinnamomum Petrophilum Nees.Chao.The PB is a synergist for pyrethrin insecticides.Thus,a mixture of 0.982 mol of CMDHS,1.27 moles of butyl carbitol,1.18 moles of NaOH was refluxed for 1.2 houres at 140℃ to give yield 84.4% of PB (purity≥89.5%).The total yield is 81.5% for CPL oil.After the wastewater of etherification was treated,CODCr can be reduced to 12 mg/L,colority can be reduced 46 time,pH can be changed to 8.

关 键 词：香桂叶油 胡椒基丁醚 二氢黄樟油素 氯甲基二氢黄樟油素 除虫菊酯 杀虫增效剂 合成 

分 类 号：TQ453.292[化学工程—农药化工] TQ450.45