氯甲基二氢黄樟油素的绿色合成新方法  

A New “Green” Route to the Synthesis of Chloromethyldihydrosafrole

作　　者：蓝文祥[1] 唐道琼 巫建国[2] 

机构地区：[1]渝州大学化学系,重庆400033 [2]四川省日用化学工业研究所,重庆400065

出　　处：《西南师范大学学报（自然科学版）》2001年第3期301-304,共4页Journal of Southwest China Normal University(Natural Science Edition)

基　　金：重庆市科学基金资助的攻关项目 (98-5 15 6)

摘　　要：报道了一种绿色合成氯甲基二氢黄樟油素的新方法 .1 0 0mol(含量 95 1% ,来自香桂叶油 )二氢黄樟油素、1 40mol(含量 95 % )多聚甲醛和 36 0mL36 %盐酸 ,在 70℃ ,剧烈搅拌 7h ,得到氯甲基二氢黄樟油素 (含量 93 4%以上 ) ,产率 98 6 % .氯甲基化反应产生的废水经过处理可以回收盐酸 ,CODCr降到 72mg/L ,色度降到 40倍 ,pH变为A “green” route to the synthesis of chloromethyldihydrosafrole [1938 32 5] is reported. Thus, a mixture of 1 00 mol of dihydrosafrole from Cinnamomum Petrophilum Leaves Oil, 1 40 moles of paraformaldehyde and 360ml of 36% hydrochloric acid was stirred for 7 0 hours at 70℃ to give 98 6% yield of chloromethyldihydrosafrole (purity ≥93 4%). 94% of hydrochloric acid can be recovered from the wastewater of chloromethylation reaction by distillation. HCl can be absorbed by the recovered hydrochloric acid to give ≥36% of hydrochloric acid, which can be used to next chloromethylation. After wastewater from the distillation is treated, COD Cr is reduced to 72 mg/L, colority is 40 time, and pH is changed to 9.

关 键 词：香桂叶油 二氢黄樟油素 氯甲基二氢黄樟油素 氯甲基化废水 合成 绿色工艺 胡椒基丁醚 废水处理 

分 类 号：TQ453[化学工程—农药化工] X383[环境科学与工程—环境工程]