环境友好型脱硫醇催化剂的研制  

Study on positive environment catalysis for mercaptan oxidation

作　　者：刘琳[1] 淳远[1] 朱建华[1] 

机构地区：[1]南京大学化学化工学院,江苏南京210093

出　　处：《宁夏大学学报（自然科学版）》2001年第2期100-101,共2页Journal of Ningxia University(Natural Science Edition)

基　　金：高等学校骨干教师资助计划项目 (2 0 0 0 143)

摘　　要：在脱硫醇反应中采用微波分散MgO的方法制备固体碱以替代传统工艺中的液体碱 .通过甲醇助剂的使用可以明显地提高催化剂的活性和寿命 .研究表明 ,催化剂性能的提高和甲醇改善催化剂表面的浸润状况 。A series of solid base derived from porous materials supporting magnesia has been prepared by use of microwave irradiation. After supporting sulfonated cobalt phthalocyanine (CoPcS), the resulting catalysts could be used in the mercaptan oxidation reaction. By introducing additives of methanol and detergent as we invented, the catalysts display a very good activity and stability in the reaction. The promotion mechanism has been identified in this paper: methanol could extract the mercaptan from the organic phase into the aqueous phase, and it could improve the soluble ability of CoPcS in water , which increase the activity of the catalysts.

关 键 词：甲醇助剂 磺化酞菁钴 环境友好型 脱硫醇催化剂 氧化镁型 固体碱 催化剂活性 

分 类 号：O643.36[理学—物理化学] X38[理学—化学]