一种聚噻吩(Pt)衍生物在液氮条件下的电致发光性能  

Electroluminescent Properties of a Kind of Polythiophen(Pt) Derivative in Liquid Nitrogen Condition

作　　者：佟拉嘎[1] 荣华[1] 藤井彰彦[2] 吉野胜美[2] 

机构地区：[1]内蒙古民族大学化学系,内蒙古通辽028043 [2]日本国,大阪大学工学部

出　　处：《发光学报》2001年第1期62-65,共4页Chinese Journal of Luminescence

摘　　要：成功地试制了用一种聚噻吩 (Pt)衍生物作发光活性物质的发光二极管 ,报导了该元件在液氮( -2 0 0℃ )中的电致发光特性。A polythiophen derivative was synthesized as an light emitting layer of LED,and its electroluminescent properties have been investigated under low and superlow temperature.The energy gap is about 2 04eV,the peak of photoluminescent spectrum is at 630nm and the emitting intensity is higher for this compound.The diode began to emit at 18V when it was in liquid nitrogen,ITO as a positive electrode,the metals as negative one (the ratio of Mg and In is 10 to 1).The intensity increases rapidly with increasing voltage and it is clear enough to be visible when the applied voltage is higher than 20V.The diode also possesses better rectification because there was no electric current when a reverse voltage was applied.It gives a red emission peaked at about 687nm.Although the diode can give red emission at room temperature in vacuum and the wavelength is still 687nm,and the applied voltage is much lower than that in liquid nitrogen,it begins to light when the voltage is 6V. The above results reveal that the plolythiophen appears some good electroluminescent properties either at room temperature or at low temperature.The studies are significant for studing the electroluminescent properties of organic high polymers,especially at low temperature.

关 键 词：聚噻吩衍生物 电致发光 发光二极管(LED) 有机高分子功能材料 低温 超低温 

分 类 号：TN312.8[电子电信—物理电子学] TB34[一般工业技术—材料科学与工程]