多孔铝激光染料镶嵌膜的荧光光谱研究  

Photoluminescence Spectra of Laser Dye Embedded in Porous Alumina

作　　者：袁淑娟[1] 赵莉丽[1] 潘志峰[1] 李清山[1] 

机构地区：[1]曲阜师范大学物理系,山东曲阜273165

出　　处：《发光学报》2001年第2期115-118,共4页Chinese Journal of Luminescence

基　　金：山东省自然科学基金资助项目 (Y98A10 0 13)

摘　　要：以多孔阳极氧化铝为基底 ,将激光染料分子RhB有效地嵌入多孔铝的孔中 ,获得多孔铝激光染料镶嵌膜。镶嵌膜的荧光光谱类似于低浓度液相染料的荧光光谱 ,但光谱线型更趋于对称。通过改变多孔铝孔的直径和深度及染料溶液浓度 ,研究光谱的变化关系 ,初步提出了多孔铝镶嵌染料膜的理想模型。Anodically oxidized porous alumina whose structure can be described as a closepacked array of columnar cells,each containing fine,regular, almost cylindrical,parallel sided pores,can be utilized as transparent host template for a variety of luminescent media.RhB laser dyes were successfully embedded in the porous alumina.We studied the photoluminescence of the compound films and compared it with the PL of the liquid dyes.It was found that the PL of the embedded dyes is like the PL of the liquid dyes at low concentration ,but the spectra symmetry of the embedded dyes is better than that of the liquid dyes.The experimental results suggest that the laser dyes mainly exist in porous alumina in form of the monomer. To clarify the detailed state of the dyes existing in the porous alumina,we have done a series of experiments.(1)Porous alumina were formed at various anodizing time in the range 30 to 90min at constant voltage 15V in 15% sulfuric acid at 25℃.The intensity of the PL of the embedded dyes increases and the peak exhibits red shift as the anodizing time grows.(2)Porous alumina were formed at various constant voltages in the range 5V to 17V for 1h in 15% sulfuric acid at 25℃.The intensity of the PL of the embedded dyes increases and the peak exhibits red shift as the anodizing voltage increases.(3)Porous alumina were formed at 15V for 1h in sulfuric acid at 25℃,and immersed in the dyes at various concentration in the solution.RhB output from the embedded layer is as a function of dye concentration in the solution.The peak of the luminescence exhibits red shift ,but severe concentration quenching is apparent for impregnation from solutions stronger than 10 -2 M/L. Finally,we put forward an idealized model to explain the state of RhB laser dyes embedded in porous alumina .The dye is roughly absorbed on the wall of the pore and mainly exists in the form of monomer.

关 键 词：多孔铝 阳极氧化 染料镶嵌膜 荧光光谱 染料激光器 

分 类 号：TN248.3[电子电信—物理电子学] O484.41[理学—固体物理]