测试温度对聚苯基缩水甘油醚的^(13)C-核磁共振谱的影响  

EFFECT OF TEMPERATURE ON ^(13)C-NMR SPECTRA OF POLY(PHENYL GLYCIDYL ETHERS)

作　　者：徐建军[1] 候可悦[1] 李立璞[1] 余云照[1] 

机构地区：[1]中国科学院化学研究所分子科学中心,北京100080

出　　处：《高分子学报》2001年第5期694-696,共3页Acta Polymerica Sinica

基　　金：;国家自然科学基金资助项目 (基金号 2 96 730 0 6 )

摘　　要：The solubility of poly(phenyl glycidyl ether)s (PPGEs) depends on the stereoregularity.Different solvents and temperatures (CDCl 3/300 K or TCE d 2/350 K)were used in 13 C\|NMR characterization of these polymers.It was necessary to investigate first the effect of temperature on the 13 C\|NMR spectra of PPGEs.It was found that all the 13 C NMR signals of PPGE were shifted to the lower magnetic field with the increase of the temperature.The temperature sensitivity of the 13 C NMR chemical shifts for different carbon atoms was different.The pendent CH 2 group was most sensitive to the temperature.The change of the 13 C\|NMR chemical shift for the pendent CH 2 group was mainly caused by the temperature change,and the effects of the solvent kind and the stereoregularity of the polymer were of minor importance.The change of temperature did not make any significant influence on the result of the stereoregularity calculation according to the 13 C\|NMR spectra for PPGEs.Utilizing the different temperature sensitivity of 13 C\|NMR signals for different groups,it is possible to separate the overlapped signals by choosing an appropriate temperature.This method was found especially useful in the 13 C\|NMR characterization of complex polymer samples.The solubility of poly(phenyl glycidyl ether)s (PPGEs) depends on the stereoregularity.Different solvents and temperatures (CDCl 3/300 K or TCE d 2/350 K)were used in 13 C\|NMR characterization of these polymers.It was necessary to investigate first the effect of temperature on the 13 C\|NMR spectra of PPGEs.It was found that all the 13 C NMR signals of PPGE were shifted to the lower magnetic field with the increase of the temperature.The temperature sensitivity of the 13 C NMR chemical shifts for different carbon atoms was different.The pendent CH 2 group was most sensitive to the temperature.The change of the 13 C\|NMR chemical shift for the pendent CH 2 group was mainly caused by the temperature change,and the effects of the solvent kind and the stereoregularity of the polymer were of minor importance.The change of temperature did not make any significant influence on the result of the stereoregularity calculation according to the 13 C\|NMR spectra for PPGEs.Utilizing the different temperature sensitivity of 13 C\|NMR signals for different groups,it is possible to separate the overlapped signals by choosing an appropriate temperature.This method was found especially useful in the 13 C\|NMR characterization of complex polymer samples.

关 键 词：^13C-NMR谱 聚苯基缩水甘油醚 测试温度 碳13-核磁共振谱 立构规整度 化学位移 

分 类 号：O657.2[理学—分析化学]