沙棘果碱提水溶多糖JS_1的结构研究  被引量:14

Studies on the Structure of -JS_1——the Water Soluble Polysaccharide Isolated by Alkaline from Hippophae Rhamnoides L.

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作  者:王桂云[1] 梁忠岩[1] 张丽萍[1] 苗春艳[1] 张翼伸[1] 费瑞[2] 

机构地区:[1]东北师范大学生命科学学院,长春130024 [2]吉林大学白求恩医学部基础医学院,长春130021

出  处:《高等学校化学学报》2001年第10期1688-1690,共3页Chemical Journal of Chinese Universities

基  金:国家自然科学基金 (批准号 :39770 847)资助

摘  要:JS 1 is the water soluble polysaccharide isolated by alkaline from Hippophae rhamnoides L.. By means of IR, GC, GC MS, 13 C NMR, periodate oxidation, Smith degradation, mathylation analysis and partial acid hydrolysis etc., JS 1 is a kind of neutral heteropolysaccharide with many branches. It consists of Ara, Xyl, Gal and Glc in a molar ratio of 1∶6∶12∶4 in turn. Its basic structure consists of a main chain composed of(1→3) linked Xyl,(1→3) linked Gal and (1→3) linked Glc residues with side chains of (1→5) linked Xyl, (1→4) linked Gal and (1→6) linked Gal residues, attached to C 2 of Xyl and C 6 of Gal residues in the main chain.JS 1 is the water soluble polysaccharide isolated by alkaline from Hippophae rhamnoides L.. By means of IR, GC, GC MS, 13 C NMR, periodate oxidation, Smith degradation, mathylation analysis and partial acid hydrolysis etc., JS 1 is a kind of neutral heteropolysaccharide with many branches. It consists of Ara, Xyl, Gal and Glc in a molar ratio of 1∶6∶12∶4 in turn. Its basic structure consists of a main chain composed of(1→3) linked Xyl,(1→3) linked Gal and (1→3) linked Glc residues with side chains of (1→5) linked Xyl, (1→4) linked Gal and (1→6) linked Gal residues, attached to C 2 of Xyl and C 6 of Gal residues in the main chain.

关 键 词:沙棘 结构 水溶性多糖JS1 提取 植物药 沙棘果碱 

分 类 号:R284.1[医药卫生—中药学] R284.2[医药卫生—中医学]

 

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