钛硅催化材料的研究进展 Ⅱ.钛硅分子筛TS-1的制备及其物化性能的研究  

Development of Titanium Silicon Catalytic Materials Ⅱ. Preparation of Titanosilicalite TS-1 and Its Physicochemical Properties

作　　者：张义华[1] 王祥生[1] 郭新闻[1] 

机构地区：[1]大连理工大学碳资源综合利用开放实验室,大连116012

出　　处：《化学进展》2001年第5期382-391,共10页Progress in Chemistry

基　　金：国家自然科学基金委和中国石油化工集团总公司联合资助 ( 2 9792 0 71)

摘　　要：钛硅分子筛 TS- 1由于其优异的催化氧化性能而受到极大关注。TS- 1的制备及基础研究是催化领域的一个热点。本文综述了近 1 0年来钛硅分子筛 TS- 1的制备研究进展 ,讨论了在合成制备过程中模板剂、钛源、硅源、碱源、晶化条件等因素对钛硅分子筛 TS- 1的影响 ,并对其物化特点进行了评述。Titanosilicalite TS-1 has attracted more attention due to its excellent catalytic properties in partial oxidation of organic compounds. The studies of the synthesis of TS-1 have become a hotspot in catalytic field. This article summarizes the advances in this field. The factors affecting on the physicochemical properties of TS-1 are discussed, including the template, the titanium source, the silicon source, the base source and the crystallization conditions. The structure characteristics of TS-1 have been reviewed.

关 键 词：钛硅分子筛TS-1 制备 选择氧化 水热法 同晶取代法 结构 酸性 表征 

分 类 号：TQ426.81[化学工程] O643.361[理学—物理化学]