Cr部分替代Mn对Ti-Zr-V-Mn-Ni贮氢合金相结构、显微组织及电化学性能的影响  

THE EFFECTS OF PARTIAL SUBSTITUTION OF Mn BY Cr ON THE PHASE STRUCTURE, MICROSTRUCTURE AND ELECTROCHEMICAL PROPERTIES OF Ti-Zr-V- Mn-Ni HYDROGEN STORAGE ALLOYS

作　　者：朱云峰[1] 潘洪革[1] 马建新[1] 李寿权[1] 葛红卫[1] 应窕[1] 王启东[1] 

机构地区：[1]浙江大学材料科学与工程系,杭州310027

出　　处：《金属学报》2001年第10期1018-1022,共5页Acta Metallurgica Sinica

基　　金：2000年度全国优秀博士学位论文基金2000052资助课题

摘　　要：研究了 Ｃｒ部分替代 Ｍｎ对 Ｔｉ－Ｚｒ－Ｖ－Ｍｎ－Ｎｉ贮氢合金相结构、显微组织及电化学性能的影响．结果表明，随着Ｃｒ的加入，合金电极的循环稳定性得到明显改善，但电极放电容量有所下降.ＸＲＤ及 ＥＤＳ分析表明，合金主要由六方结构的Ｃ１４ Ｌａｖｅｓ母相和立方结构的ＴｉＮｉ型第二相构成，Ｃｒ替代后，合金中出现了立方结构的Ｖ－Ｃｒ固溶相 金相显微组织显示，铸态和退火态合金均由连续的 Ｃ１４ Ｌａｖｅｓ相基体以及 ＴｉＮｉ型树枝晶第二相组成．AB(2) type Ti-Zr-V-Mn-Ni-based Laves phase hydrogen storage alloys have a very high initial electrochemical discharge capacity, but the capacity decreases drastically within several charging-discharging cycles in KOH electrolyte which impede their applications as the negative electrode materials in Ni-MH batteries. In is work, Mn was partially substituted by Cr in the Ti-Zr-V-Mn-Ni hydrogen storage alloy and the effects of Cr substitution on the phase structure, microstructure and electrochemical properties of the alloys have been investigated. It is found that the cycle durability of the alloy electrodes have been greatly improved with Cr substitution despite the decrease of discharge capacities. Based on the XRD and EDS analysis, the alloys are mainly composed of C14 Laves phase matrix with hexagonal structure and TiNi type secondary phase with bcc structure. With Cr substitution, another V-Cr solid solution with bee structure appears. The metallographic observation shows that both the as cast and annealed alloys consist of a continuous C14 Laves phase matrix and TiNi type secondary phase with dendritic structure.

关 键 词：贮氢合金 相结构 显微组织 电化学性能 锰 铬 钛合金 

分 类 号：TG139.7[一般工业技术—材料科学与工程] TG146.23[金属学及工艺—合金]