烯丙基氯氨解制备烯丙基胺  

Synthesis of Allylamine by Ammonolysis of Allyl Chloride

作　　者：刘锋[1] 张淑芬[1] 杨锦宗[1] 任鹏[1] 

机构地区：[1]大连理工大学精细化工国家重点实验室,辽宁大连116012

出　　处：《精细化工》2001年第11期678-681,共4页Fine Chemicals

基　　金：国家自然科学基金资助项目 ( 2 0 0 76 0 0 6 )~~

摘　　要：讨论了烯丙基氯在液氨和乙醇中制备烯丙基胺的氨解反应 ,在液氨中 ,n(氨 )∶n(烯丙基氯 )∶n(氯化铵 ) =2 0∶1∶1时 ,45℃反应 8h ,产物中w(伯胺 ) =46 8%。乙醇为溶剂时 ,n(氨 )∶n(烯丙基氯 ) =2 0∶1,在温度 40℃反应 8h ,产物中w(伯胺 ) =78 83 % ,用均匀设计对乙醇为溶剂的实验进行了优化 。Synthesis of allylamine by ammonolysis of allyl chloride in ethanol and liquid ammonia in the presence of CuCl was investigated. In liquid ammonia at mole ratio NH3 : C3H5Cl : NH4Cl = 20 : 1 : 1 and temperature = 45°C, mass percentage of monoallylamine in the product was 46.8%. Using ethanol as solvent at mole ratio NH3 : C3H5Cl = 20:1 and temperature = 40°C, mass percentage of monoallylamine in the product was 78.83%. Uniform design was applied to optimize the experiment.

关 键 词：烯丙基胺 烯丙基氯 氨解 制备 

分 类 号：TQ226.3[化学工程—有机化工] TQ203