四(对-十四酰氧基)苯基卟啉过渡金属配合物的合成与表征  

Syntheses and characterization of tetra (4-n-tetradecanoyloxyphenyl) porphyrin complexes

作　　者：李晓晔[1] 吴红[1] 柳巍[1] 姜茹[1] 

机构地区：[1]第四军医大学基础部化学教研室,陕西西安710033

出　　处：《第四军医大学学报》2001年第19期1763-1765,共3页Journal of the Fourth Military Medical University

基　　金：国家自然科学基金资助项目 ( 5 97830 0 1)

摘　　要：目的　合成相变温度较低、相区宽的卟啉液晶 5 ,10 ,15 ,2 0 -四 (对 -十四酰氧基 )苯基卟啉 [简称 TMPPH2 ]及其 Mn(III) ,Fe(III) ,Co(II) ,Ni(II) ,Cu(II) ,Zn(II)配合物 .方法　用元素分析、紫外可见光谱、红外光声光谱、核磁共振氢谱和摩尔电导等现代分析方法表征了它们的组成和结构 ,并用DSC和偏光显微镜研究了配体及其锌配合物的液晶行为 .结果　配体及锌配合物具有液晶性质 ,且锌配合物的液晶相相变温度始于 0 .6 18℃ ,相区宽达 77℃ .AIM To synthesize tetra (4 n tetradecanoyloxyphenyl) porphyrins Liquid crystal with lower temperature of phase change and its Mn(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes. METHODS The structures of complexes were determined by elemental analysis, UV Vis, FTIR photoacoustic spectrum, 1H NMR and molar conductance. The domains of stability and the structure of the liquid crystalline phases were determined by optical microscopy and differential scanning calorimerials (DSC). RESULTS Ligand and its Zn(II) complex had liquid crystalline behavionr. The phase transition temperature of Zn(II) complex was at 0.618℃, and a mesophase range about 77℃. CONCLUSION Liqand and its Zn(II) complex can be used as a liquid crystalline material.

关 键 词：四(对-十四酰氧基)苯基卟啉 配合物 卟啉液晶 合成 表征 

分 类 号：O626.13[理学—有机化学] O641.4[理学—化学]