手性Salen金属配合物水解拆分环氧氯丙烷的反应动力学  

Reaction Kinetics of Hydrolysis Resolution of Epichlorohydrin Catalyzed by Chiral Salen Metal Complex

作　　者：刘涛[1] 阮文娟[1] 张玉玲[1] 朱志昂[1] 陈荣悌[1] 

机构地区：[1]南开大学化学系,天津300071

出　　处：《催化学报》2001年第5期497-500,共4页

基　　金：国家自然科学基金资助项目 ( 2 98710 18)

摘　　要：The reaction kinetics of hydrolysis resolution of racemic epichlorohydrin to chiral chloropropandiol and optically active epichlorohydrin, catalyzed by chiral salen metal complexes, was studied by using gas chromatography. The effects of temperature, catalyst type and catalyst concentration on the reaction rate were explored. On the experimental results, some kinetic regularity for the reaction has been obtained.The reaction kinetics of hydrolysis resolution of racemic epichlorohydrin to chiral chloropropandiol and optically active epichlorohydrin, catalyzed by chiral salen metal complexes, was studied by using gas chromatography. The effects of temperature, catalyst type and catalyst concentration on the reaction rate were explored. On the experimental results, some kinetic regularity for the reaction has been obtained.

关 键 词：手性SALEN金属配合物 水解拆分 环氧氯丙烷 反应动力学 催化剂 

分 类 号：O643.1[理学—物理化学]