二氰基二硫纶·联吡啶过渡金属配合物的电子吸收光谱和荧光光谱  

Electronic Absorption Spectra and F luorescence Spectra of Transition Metal Complexes with Dicyanodithio lene and Bipyridine

作　　者：王守兴[1] 柏冬[2] 彭正合[1] 秦子斌[1] 

机构地区：[1]武汉大学化学系,武汉4300722 [2]枣庄师专化学系,枣庄277160

出　　处：《无机化学学报》2001年第6期878-882,共5页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助课题(NO;29771025)

摘　　要：本文得到二氰基二硫纶·联吡啶过渡金属配合物MmntbpyM=Mn、Fe、Co、Ni、Cu、Znmnt=二氰基二硫纶bpy=联吡啶在室温下不同溶剂中的电子吸收光谱和荧光发射光谱及固态荧光光谱讨论了该类配合物的电子吸收光谱和荧光光谱与中心金属离子及溶剂性质间的关系。The electronic absorption spectra and fluorescence spectra of the title compounds [M(mnt) (bpy)] (M = Mn (II), Co (II), Fe (II), Ni (II), Cu (II), Zn (II); mnt = dicyanodithiolene; bpy = bipyridine) have been obtained in the solid and in various solevents at room temperature, and the relationships between the two kind spectra and the metal ions and the solvents were discussed, respectively.

关 键 词：二氰基二硫纶 过渡金属配合物 电子吸收光谱 荧光光谱 联吡啶 

分 类 号：O641.4[理学—物理化学]