Synthesis and Crystal Structure of t he Complex of Antimony Trichloride and Dioxane  

三氯化锑和二氧杂环己烷配合物[SbCl_(3)·{(CH_(2))_(4)O_(2)}_(1.5)]的合成与晶体结构

作　　者：臧祥生[1] 陈娅如[1] 栾绍嵘[1] 钟国清[2] 郭应臣[3] 

机构地区：[1]华东理工大学化学系,上海200237 [2]四川畜牧兽医学院,重庆402460 [3]南阳师范学院化学系,南阳473061

出　　处：《无机化学学报》2001年第6期901-904,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.29771011)

摘　　要：New solid complex of the antimony trichloride and dioxane was obtained th rough a reaction of the dioxane and the absolute methanol solution of the antimony trichloride.The formula of the complex is[SbCl_(3)·{(CH_(2))_(4)O_(2)}_(1.5)].The crystal structure of the comple x belongs to cubic system,space group I-43d,a=17.1417(5)?,Z=16.The trivalent antimony ion not only bonds directly to three chlorine anions,but also is co ordinated by three oxygen atoms of th e dioxane molecules.Two oxygen atoms in a dioxane molecule wi ll coordinate to different antimony ions,respectively.

关 键 词：dioxane complex of antimony trichloride synthesis crystal structure 

分 类 号：O612.5[理学—无机化学]