聚有机硅倍半氧烷热解研究进展  

Advancement in the Study on Pyrolysis of Polysilsesquioxane

作　　者：马军[1] 冯庆阳[1] 张晓莉[1] 施良和[1] 徐坚[1] 

机构地区：[1]中国科学院化学研究所,北京100080

出　　处：《高分子通报》2001年第5期34-38,共5页Polymer Bulletin

基　　金：国家自然科学基金项目 (编号 :2 0 0 74 0 3 9) ;中科院化学所高分子物理与化学国家重点实验室基金 (0 0 1 3 0 1 )

摘　　要：国防航空工业的发展需求高性能陶瓷 ,尤其是纳米陶瓷。聚有机硅倍半氧烷可作为前躯体 ,通过热解制备陶瓷。该方法操作简便 ,易于控制。本文综述了国外有关聚有机硅倍半氧烷热解理论与应用研究近况 ,并对这一领域的发展进行了展望。The major aspects of the theoretical study on use of polysilsesquioxanes as precursors to silicon oxy carbide ceramics through pyrolysis at elevated temperatures in inert atmospheres and a variety of applications, including matrices, infiltrates and coatings in ceramic matrix composites, were reviewed in this paper. Several methods of pyrolysis have been mentioned. The conversion of silsesquioxanes to silicon oxy carbide ceramics, the pyrolysis mechanism and the final products were discussed. Its coming developments are given.

关 键 词：聚有机硅倍半氧烷 热解 硅-碳-氧陶瓷 前驱体 理论研究 应用研究 

分 类 号：O634[理学—高分子化学]