微波照射下膦酰基/硫甲基烯酮硫代缩醛和N-取代膦酰基/硫甲基硫代碳酸酯的合成  

Synthesis of Novel Phosphonyl/S-methyl Ketene Thioacetals and N-Substituted Phosphonyl/S-methyl Thiocarbonates under Microwave Irradiation

作　　者：陈凯[1] 杨华铮[1] 刘准[1] 胡方中[1] 张春香[1] 

机构地区：[1]南开大学元素有机化学研究所

出　　处：《有机化学》2001年第9期690-692,共3页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金 (Nos.2 9772 0 2 0 ;2 9832 0 5 0 );教育部博士点专项基金资助项目

摘　　要：在微波照射下方便、高收率地合成了新奇的膦酰基杂环的合成子膦酰基 /硫甲基烯酮硫代缩醛和N 取代膦酰基/硫甲基硫代碳酸酯 ,实验表明微波照射大大加快了反应速率和提高了反应产率。Phosphonyl/S-methyl ketene thioacetals and N-substituted phosphonyl/S-methyl thiocarbonates-novel kinds of synthons for the synthesis of phosphonyl heterocyclic compounds were conveniently synthesized under microwave irradiation with high yields. It showed that the reaction process was significantly enhanced using microwave heating.

关 键 词：膦酰基/硫甲诺烯酮硫代缩醛 N-取代膦酰基/硫甲基硫代碳酸酯 微波照射 合成 有机膦农药 膦酰基杂环化合物 

分 类 号：TQ450[化学工程—农药化工]