茂金属—Z/N催化体系乙烯聚合研究  

Polymerization of ethylene with metallocene-Z/N catalyst

作　　者：冯玉涛[1] 朱博超[1] 

机构地区：[1]中国石油兰州石化公司石油化工研究院,甘肃兰州730060

出　　处：《石化技术与应用》2001年第4期282-282,共1页Petrochemical Technology & Application

基　　金：中国石油天然气集团公司资助项目 (合同号 :2 0 0 90 9-0 1)

摘　　要：A novel polyethylene production process by gas polymerization and slurry polymerization based on metallocene-Z/N catalyst system were reported. The polyethylene thus produced had two melting points with broad relative molecular mass distribution ( MWD ). The relative molecular mass, MWD , melt flow rate determined by the ratio of Ti/Zr and of H 2/C 2H 4. The tensile strength of polyethylene produced by metallocenc-Z/N catalyst was higher than that of LL103A.A novel polyethylene production process by gas polymerization and slurry polymerization based on metallocene-Z/N catalyst system were reported. The polyethylene thus produced had two melting points with broad relative molecular mass distribution ( MWD ). The relative molecular mass, MWD , melt flow rate determined by the ratio of Ti/Zr and of H 2/C 2H 4. The tensile strength of polyethylene produced by metallocenc-Z/N catalyst was higher than that of LL103A.

关 键 词：茂金属 Z/N催化体系 乙烯 气相聚合 淤浆聚合 

分 类 号：TQ325.12[化学工程—合成树脂塑料工业] TQ320.4