Omega沸石的改性研究  被引量:2

STUDY ON MODIFICATION OF OMEGA ZEOLITE

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作  者:王殿中[1] 李明罡[1] 何鸣元[1] 

机构地区:[1]石油化工科学研究院,北京100083

出  处:《石油炼制与化工》2001年第10期30-32,共3页Petroleum Processing and Petrochemicals

摘  要:为改善Omega沸石热及水热稳定性的缺陷 ,以水热焙烧结合化学脱铝的方法对Omega沸石进行了脱铝改性 ,并考察了改性沸石的结构稳定性及裂化性能。结果表明 ,改性处理后 ,脱铝Omega沸石的结构水热稳定性提高 ,80 0℃水热处理 4h ,结晶保留度可从 38%提高到 6 0 % ;结构富含中孔 ;中强酸所占比例增加 ;对重油的转化能力增加。Omega zeolite was dealuminated by hydrothermal and chemical methods to increase its structure stability for improving the defects of its thermal and hydrothermal stabilities. The structural stability and cracking performance of the modified zeolite were investigated. It was found that the structural hydrothermal stability was improved after the zeolite being treated under 800 ℃/4 h hydrothermal condition, its crystallinity retention was increased from 38% to 60%. The modified Omega zeolite possessed abundant mesopores, more medium strong acid and higher heavy oil conversion.

关 键 词:Omega沸石 水热稳定性 改性 水热焙烧 化学脱铝 石油烃 裂化能力 

分 类 号:TE624[石油与天然气工程—油气加工工程]

 

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