二茂铁电解合成法的研究  

Studies on Electrolytic Synthesis Method of Ferrocene

作　　者：李助兴[1] 张玉鸿[2] 

机构地区：[1]内蒙古大学化学系 [2]内蒙古教育学院化学系

出　　处：《内蒙古师范大学学报（自然科学汉文版）》1991年第3期32-35,共4页Journal of Inner Mongolia Normal University(Natural Science Edition)

摘　　要：本文研究了以0.5M溴化钠为支持电解质、N,N—二甲基甲酰胺(DMF)为溶剂的体系中电解法合成二茂铁的主要条件。收率按环戊二烯加入量计算为42.6%。测定了产品的熔点、元素百分含量及红外光谱图,所得结果与文献值相符。In the paper primary conditions of electrolytical synthesis of ferrocene were studies in this system, 0.5M NaBr used as supporting electrolyte, N. N-dimethylformamide (DMF) as solvent. The rate of product was 42.6% according to the adding quantity of cyclopentadiene. The m. p of product, percent content of element and IR spectra were determined. These results coincide with those of literature values.

关 键 词：二茂铁 合成 电解法 

分 类 号：O627.81[理学—有机化学]