杯[4]芳烃-5,11,17,23-四磺酸钠的合成  

The Synthesis of Calixarenes-5,11,17,23-tetrasulfonic acid, Tetrasodium Salt

作　　者：范平[1] 蔡晨新[1] 葛春华[1] 辛西牧[1] 李鸿图[1] 

机构地区：[1]辽宁大学化学科学与工程学院,辽宁沈阳110036

出　　处：《辽宁大学学报（自然科学版）》2001年第4期383-384,共2页Journal of Liaoning University：Natural Sciences Edition

基　　金：辽宁省自然科学基金资助 (批准号 :0 0 2 0 82 );辽宁大学科研基金资助

摘　　要：In this paper,Calixarenes 5,11,17,23 tetrasulfonic acid, tetrasodium salt was synthesized by the reaction of calixarenes and H 2SO 4. The yield of the Calixarenes 5,11,17,23 tetrasulfonic sodiums was improved to 20%～30% using the method that the reactant (filitrated H 2SO 4) was dissolved in a little amount of NaCl saturated solution and then the water was volatilized at room temperature.In this paper,Calixarenes 5,11,17,23 tetrasulfonic acid, tetrasodium salt was synthesized by the reaction of calixarenes and H 2SO 4. The yield of the Calixarenes 5,11,17,23 tetrasulfonic sodiums was improved to 20%～30% using the method that the reactant (filitrated H 2SO 4) was dissolved in a little amount of NaCl saturated solution and then the water was volatilized at room temperature.

关 键 词：芳烃-5 11 17 23-四黄酸钠 磺化反应 超分子化学 合成 配位作用 对-叔丁基苯酚 

分 类 号：O614.112[理学—无机化学] O623.84[理学—化学]