含氮大环化合物的研究  

Studies on Azacrown Ether Compounds and Macrocyclic Polyamines

作　　者：吴成泰[1] 何永炳[1] 付恩琴[1] 

机构地区：[1]武汉大学化学与分子科学学院,

出　　处：《有机化学》2001年第11期914-922,共9页Chinese Journal of Organic Chemistry

基　　金：国家自然科学基金

摘　　要：总结十五年来在氮杂冠醚和大环多胺的合成和性质研究方面的主要成果:氮杂冠醚和大环多胺合成的方法学研究,氮杂冠醚和大环多胺的NMR研究,含氮杂冠醚结构单元的吲哚啉螺苯并吡喃类信息接受体的合成和性质研究,桥连环糊精二聚体的分子识别研究.This paper summarizes the main research of azacrown ether compounds and macrocyclic polyamines in our group from 1985 to 2000. It consists four parts: (1)Research of synthetic method of a series new macrocyclic compounds: benzoazacrown ether, azacrown ethers containing central functional group and their N-pivot lariat derivatives, Schiff's azacrown ethers and macrocyclic polyamines containing pyridine or bipyridine ring etc. (2)Application of NMR in the complexation of N-substituted benzocrown ethers with p-toluene diazonium fluoroborate, conformation of azacrown ether containing central group, and research of dilution shift effect. (3)Research of synthesis and photochromism of crowned indolinospiropyrans as artifical signaling recepter. (4)Synthesis and molecular recognition of cyclodextrin dimers.

关 键 词：氮杂冠醚 大环多胺 螺吡喃 环糊精 合成 光致变色 核磁共振 分子识别 超分子化学 

分 类 号：O626[理学—有机化学] O641.3[理学—化学]