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作 者:龙兴贵[1] 赵鹏骥[1] 彭述明[1] 罗顺忠[1] 姚书久[1] 张小安[1] 李海容[1]
机构地区:[1]中国工程物理研究院核物理与化学研究所,四川绵阳621900
出 处:《化学研究与应用》2001年第6期689-691,694,共4页Chemical Research and Application
摘 要:Four ytterbium deuteride samples with D/Yb atomic ratio of 2.90、2.53、2.23 and 2.06 were prepared under high pressure metal system at 400℃,and initial deuterium pressure is 6.53MPa、3.41MPa and 1.32MPa respectively.Results indicate that satureated time of deuterium by ytterbium sample and D/Yb atomic ratios are correlated with initial deuterium pressure.XRD analytical results indicate that YbD 2.90 has a facc structure with a=0.5205nm.YbD 2.90 decomposed at 600℃,the product is YbD 2.06 and it has two phases,they are orthorhombic and another face center cubic structure.YbD 2.53 and YbD 2.23 are composed by orthorhombic and face center cubic ytterbium deuterides.Four ytterbium deuteride samples with D/Yb atomic ratio of 2.90、2.53、2.23 and 2.06 were prepared under high pressure metal system at 400℃,and initial deuterium pressure is 6.53MPa、3.41MPa and 1.32MPa respectively.Results indicate that satureated time of deuterium by ytterbium sample and D/Yb atomic ratios are correlated with initial deuterium pressure.XRD analytical results indicate that YbD 2.90 has a facc structure with a=0.5205nm.YbD 2.90 decomposed at 600℃,the product is YbD 2.06 and it has two phases,they are orthorhombic and another face center cubic structure.YbD 2.53 and YbD 2.23 are composed by orthorhombic and face center cubic ytterbium deuterides.
关 键 词:氘化镱 X-射线衍射 晶体结构 氘 吸氘性能 金属镱
分 类 号:TL627[核科学技术—核技术及应用]
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