二胺-Co(Ⅱ)氧合配合物的固相合成、表征及其性能的研究  

Synthesis and Characterization of Diamine Co(Ⅱ) Oxygenated Complexes by Solid Phase Reaction

作　　者：曹艳霞[1] 王吉德[1] 岳凡[1] 迟姚玲[1] 

机构地区：[1]新疆大学化学系,乌鲁木齐830046

出　　处：《化学通报》2001年第12期789-792,共4页Chemistry

基　　金：国家自然基金资助项目 (2 946 10 0 3)

摘　　要：采用固相方法合成了两个二胺 Co(II)配合物 ,并研究了其吸氧反应 ;通过元素分析、热分析等测试手段研究了氧合配合物的性质 ,确定了其组成 ,探讨了配体结构对配合物吸氧的影响 。Two complexes of Co(Ⅱ) with diamine were systhesized by solid phase reaction and their oxygenation reaction were studied. The oxygenated complexes were characterized with elemental analysis and thermal analysis. The effects of ligand structure on oxygenation and the possible solid phase reaction mechanisms of oxygenated compelexes were discussed.

关 键 词：钴 氧合反应 固相合成 表征 性能 Co(Ⅱ) 二胺 氧合配合物 

分 类 号：O641.4[理学—物理化学]