8-羟基喹啉-邻菲罗啉-稀土三元固体配合物的合成和表征  

SYNTHESIS AND CHARACTERIZATION OF TERNARY SOLID COMPLEXES OF RARE EARTHS-OXINE-PHENANTHROLINE

作　　者：胡明[1] 赵永亮[1] 

机构地区：[1]内蒙古大学化学化工学院,内蒙古呼和浩特010021

出　　处：《化学研究与应用》2001年第5期560-562,共3页Chemical Research and Application

基　　金：内蒙古自然科学基金资助项目 ( 990 30 3 -4 )

摘　　要：In the anhydrous alcohol solution of the ternary solid complexes of rare earths oxine phenanthroline have been sythesized.The composition of the RE complexes are RE(Phen)(Oxine) 2Cl·H 2O(RE=La 3+ ,Pr 3+ ,Nd 3+ ,Sm 3+ ,Eu 3+ ,Gd 3+ ,Tb 3+ ,Dy 3+ ) has becn obtained by the experiments of elemental analysis,IR spectra,UV spectra and molar conductivity.The data of IR spectra show that the bonds of RE O and RE N exist in the RE phen oxine complexes.In the anhydrous alcohol solution of the ternary solid complexes of rare earths oxine phenanthroline have been sythesized.The composition of the RE complexes are RE(Phen)(Oxine) 2Cl·H 2O(RE=La 3+ ,Pr 3+ ,Nd 3+ ,Sm 3+ ,Eu 3+ ,Gd 3+ ,Tb 3+ ,Dy 3+ ) has becn obtained by the experiments of elemental analysis,IR spectra,UV spectra and molar conductivity.The data of IR spectra show that the bonds of RE O and RE N exist in the RE phen oxine complexes.

关 键 词：稀土配合物 8-羟基喹啉 邻菲罗啉 合成 表征 三元固体配合物 

分 类 号：O614.33[理学—无机化学]