硼酸钠/甲阶酚醛树脂配合物结构和反应机理  

Complexes Structure of the Sodium Borate and Resol Phenol-formaldehyde Resin and Their Reaction Mechanism

作　　者：谭晓明[1] 黄乃瑜[1] 尚永华[2] 李焰[2] 

机构地区：[1]华中科技大学材料科学与工程学院 [2]华中科技大学化学系

出　　处：《华中科技大学学报（自然科学版）》2001年第8期93-95,共3页Journal of Huazhong University of Science and Technology(Natural Science Edition)

基　　金：塑性成形模拟及模具技术国家重点实验室开放基金资助项目 (0 1 6 )

摘　　要：通过对溶液 pH值的测定和红外光谱分析 ,研究了在水溶液中硼酸钠与甲阶酚醛树脂的配位反应、产物结构和反应机理 .结果表明 :在室温下硼酸钠能与甲阶酚醛树脂发生配位 ,并产生H+ 使溶液的 pH值降低 ;在水溶液中硼酸钠水解产生B(OH) 3,与甲阶酚醛树脂中的酚羟基和邻位羟甲基经过配位和酯化反应形成一个含有 2个O原子和The complexes structure of sodium borate and resol phenol formaldehyde resin and their reaction mechanism are investigated by measuring pH and analyzing infrared spectroscopy. The results that the complexation reaction between sodium borate and resol phenol formaldehyde can be carrid out quickly in the aqueous solution at room temperature. The reaction can produce H + and decrease the pH in the resin solution. The reaction takes place in phenol hydroxyl groups and hydroxymethyl groups in adjacent position on the aromatic ring in the resin. The complexes is a hexatomic ring containing two oxygen atoms and one boron atom.

关 键 词：甲阶酚醛树脂 硼酸钠 配合物 结构 反应机理 配位反应 酯化反应 

分 类 号：O614.112[理学—无机化学] O632.72[理学—化学]