马来酸酐-苯乙烯熔融接枝聚丙烯的影响因素及其性能研究  

STUDY OF MELT FREE RADICAL GRAFTING OF MALEIC ANHYDRIDE AND STYRENE ONTO POLYPROPYLENE AND ITS PROPERTIES

作　　者：谢续明[1] 李颖[1] 张景春[1] 杨讯[2] 

机构地区：[1]清华大学化工系高分子研究所材料科学与工程研究院教育部先进材料重点实验室,北京100084 [2]同济大学土建系,上海200333

出　　处：《高分子学报》2002年第1期7-12,共6页Acta Polymerica Sinica

基　　金：华南理工大学聚合物成型装备国家工程研究中心科学与技术基金资助项目 (基金号 99 0 0 1)

摘　　要：用单螺杆挤出机制备了马来酸酐 (MAH) 苯乙烯 (St)对聚丙烯 (PP)的多组分单体自由基熔融接枝体系 .研究证实了当两种单体物质的量比约为 1∶1时 ,接枝物的接枝率最高 ,而熔体流动速率 (MFR)最大 .对反应体系影响因素的研究表明单体用量和引发剂用量对不同单体用量比的系列接枝物的接枝率会产生不同的影响 ;另外 ,单体用量增加 ,接枝物的MFR减小 ,过氧化二异丙苯 (DCP)用量增加 ,接枝物的MFR增加 .对多单体熔融接枝聚丙烯PP g (MAH co St)的力学性能研究发现 ,选用合适的单体用量比、单体用量和DCP用量时 。Free radical melt-grafting of the multi-monomer system of maleic anhydride (MAH)/styrene (St) onto polypropylene (PP) has been studied by means of a single-screw extruder. It has been proved that the grafting degree and the melt flow rate (MFR) of the grafted PP both reached maximum points when molar ratio of the two monomer was 1 : 1. Monomer concentration and DCP content were found to have different effects on grafting level of the grafted PP obtained in systems with different concentration ratio of MAH to St. Besides, the MFR values of the grafted PP decreased with increasing monomer concentration and increased with increasing DCP content. The multi-monomers melt grafted PP, i . e . PP-g-(MAH-co-St) was investigated for its properties. Excellent mechanical properties were obtained when suitable monomer concentration ratio, monomer concentration and DCP content were applied to the grafting system.

关 键 词：聚丙烯 熔融接 马来酸酐 苯乙烯 塑料 力学性能 改性 

分 类 号：TQ316.6[化学工程—高聚物工业]