晶体包合物反式-9,10-二氢-9,10-二(1-萘基)-9,10-菲二醇·二环己胺的结构研究  

Crystal Structure of the Inclusion Compound trans-9, 10-dihydro-9, 10-di(1-naphthyl)-9, 10-penanthrenediol·dicyclohexylamine

作　　者：朱峰[1] 林永成[1] 郭文生[2] 

机构地区：[1]中山大学化学与化学工程学院,广东广州510275 [2]辽宁大学化学科学与工程学院,辽宁沈阳110036

出　　处：《中山大学学报（自然科学版）》2002年第1期39-42,共4页Acta Scientiarum Naturalium Universitatis Sunyatseni

基　　金：国家自然科学基金资助项目 (39370 810 )

摘　　要：制得了晶体包合物反式_9,10_二氢_9,10_二 (1_萘基 )_9,10_菲二醇·二环己胺 ,通过熔点测定 ,IR ,粉末XRD对其进行了表征 ,用1 HNMR测定其分子摩尔比为 1∶2 ,X_射线衍射结果表明晶体属于正交晶系 ,空间群为Pnca,晶胞参数 :a =1 6 714(3) ,b=1 6 875 ,c=1 72 2 4(3)nm ,V =4 85 80 (15 )nm3 ,Z =8。Crystalline inclusion compound trans-9, 10-dihydro-9, 10-di(1-naphthyl)-9, 10-penanthrenediol·dicyclohexylamine was prepared and confirmed by means of IR and powder XRD. The host-guest molar ratio was determined by 1H NMR. The crystal structure of the 1∶2 inclusion compound was determined by XRD. The crystal belongs to orthorhombic system, space group Pnca. The unit cell parameters are:a=1.671 4(3) nm,b=1.687 5 nm,c=1.722 4(3) nm,V=4.858 0(15) nm 3 and Z=8. The inclusion compound exhibits O-H...N hydrogen bonding interactions.

关 键 词：反式-9 10-二氢-9 10-二(1-萘基)-9 10-菲二醇 二环己胺 晶体包合物 X-射线衍射 晶体结构 正交晶系 

分 类 号：O625.155[理学—有机化学] O624.6[理学—化学]