两种含硫席夫碱及其铜(Ⅱ)配合物的合成  

Synthesis of two surfur-containing Schiff bases and their copper (Ⅱ) complexes

作　　者：周双生[1] 谢复新[2] 倪诗圣[2] 

机构地区：[1]安徽中医学院药学系,合肥230038 [2]安徽大学化学系,合肥230039

出　　处：《化学试剂》2001年第5期261-262,303,共3页Chemical Reagents

基　　金：国家自然科学基金资助课题

摘　　要：合成了 2 ,5 -噻吩二甲醛双缩 (2 -羟基乙胺 ) (H2 L1)和 2 ,5 -噻吩二甲醛双缩邻氨基苯硫酚 (H2 L2 ) 2种含硫席夫碱以及它们的铜 ( )配合物 ,经元素分析、红外光谱和核磁共振谱表征 ,并测定了它们的磁化率和电导率 ,确定了配合物的组成。Two novel surfur containing Schiff bases 2,5 bis [formyl (2 hydroxyethylamine)] thiophene (H 2L 2) and 2,5 bis [formyl (2 mercaptoaniline)] thiophene (H 2L 2) were reported.The copper (Ⅱ) complexes with this two ligands were prepared.These compounds were characterized by elemental analysis,IR, 1HNMR,conductivity and magnetic susceptibility.The possible structures for the two complexes were conjectured.

关 键 词：含硫席夫碱 配合物 合成 铜 磁性 组成 元素分析 

分 类 号：O614.121[理学—无机化学] O625.632[理学—化学]