手性双噁唑啉铜配合物在不对称合成中的应用  

The Application of Chiral Bis-oxazoline Copper Complexes to the Asymmetric Synthesis

作　　者：陈本顺[1] 陈晓[1] 徐效华[1] 廖仁安[1] 

机构地区：[1]南开大学元素有机化学研究所国家重点实验室,天津300071

出　　处：《化学通报》2001年第10期614-620,共7页Chemistry

摘　　要：综述了手性双唑啉配体的主要结构类型 ,并讨论了手性双唑啉铜配合物在不对称Diels Alder反应、Ene反应、Mukaiyamaadol反应、烯丙基氧化、环丙烷化、氮杂环丙烷化等反应中的应用。The kinds of chiral bis\|oxazoline ligands and catalysts were summarized and the activities of catalysts were compared.The application of chiral bis\|oxazoline copper complexes to the asymetric Diels\|alder reaction,ene reaction allylic oxidation,cyclopropanation of olefins and aziridination of olefins were also discussed.

关 键 词：双E唑啉 手性双E唑啉酮配合物 不对称合成 配体 应用 

分 类 号：O621[理学—有机化学]