新型有机电双稳态材料的设计和性质  

Design and Properties of a Novel Electrically Bistable Organic Material

作　　者：武芳卉[1] 周峥嵘[1] 王全瑞[1] 丁宗彪[1] 陶凤岗[1] 夏 燚 徐 伟[2] 华中一[2] 

机构地区：[1]复旦大学化学系,上海200433 [2]复旦大学材料科学系,上海200433

出　　处：《化学学报》2002年第1期4-6,共3页Acta Chimica Sinica

基　　金：国家自然科学基金(No.59703003);教育部重点科技基金资助项目.

摘　　要：随着微电子器件尺度的不断缩小,可作为非硅存储器的有机电双稳材料已成为分子电子学研究的一大热点[1,2].与传统的无机材料相比,有机材料具有作用体积小,容易获得,制作工艺简单等优点.A novel spiro-annulated compound 3, 9-di (dicyanomethylene)-2, 4, 8, 10-tetrathiaspiro [5, 5] undecane (SCN) has been designed and synthesized as an organic electrically bistable material. The crystal structure of SCN has been studied. Silver/copper-SCN charge transfer complexes were obtained and both of them show good bistable states and thermal stability.

关 键 词：电双稳态 四硫杂螺环化合物 晶体结构 电荷转移配合物 合成 有机电双稳态材料 分子设计 

分 类 号：TP333[自动化与计算机技术—计算机系统结构]