[Ni(dien)_2]_2[Mn(NCS)_6]·H_2O的合成、晶体结构  

Synthesis and Crystal Structure of[Ni(dien)_2]_2[Mn(NCS)_6]·H_2O

作　　者：沈良[1] 徐迅[2] 徐端钧[3] 徐元植[3] 

机构地区：[1]杭州师范学院化学系,杭州310012 [2]京都大学大学院理学研究科 [3]浙江大学化学系,杭州310027

出　　处：《无机化学学报》2002年第3期309-312,共4页Chinese Journal of Inorganic Chemistry

基　　金：国家自然科学基金资助项目(No.29973036)

摘　　要：The crystal of [Ni（dien）2]2[Mn（NCS）6]·H2O was synthesized and the structure of its single crystal was determined by X ray diffraction. The crystal is monoclinic system, space group P21/c with a=16.544（3）,b=15.137（2）, c=17.334（3）?, β=99.90（1）°, V=4276.3（12）?3, Z=4, Dc=1.479g·cm-3, Mr=951.55, F（000）=1998, μ=1.489mm-1, R=0.0399, Rw=0.0958. IR was also determined.The crystal of [Ni(dien)_2]_2[Mn(NCS)_6]·H_2O was synthesized and the structure of its single crystal was determined by X ray diffraction. The crystal is monoclinic system, space group P21/c with a=16.544(3),b=15.137(2), c=17.334(3)?, β=99.90(1)°, V=4276.3(12)?3, Z=4, Dc=1.479g·cm-3, Mr=951.55, F(000)=1998, μ=1.489mm-1, R=0.0399, Rw=0.0958. IR was also determined.

关 键 词：硫氰酸根 二乙烯三胺 多核配合物 晶体结构 镍 锰 合成 

分 类 号：O614.813[理学—无机化学] O614.711[理学—化学]