卤素离子与苯骈三氮唑协同成膜动力学的体声波传感技术研究  

BAW Study on Growth Kinetics of Synergistic Films of Benzotriazole (BTA) and Halide Ion

作　　者：罗胜联[1] 陈金华[1] 陈凡[1] 魏万之[1] 

机构地区：[1]湖南大学化学化工学院,湖南长沙410082

出　　处：《湖南大学学报（自然科学版）》2002年第1期52-57,共6页Journal of Hunan University:Natural Sciences

基　　金：国家自然科学基金 (2 0 0 770 0 6 ) ;湖南省自然科学基金 (0 0 JJY2 0 14 )资助课题

摘　　要：采用体声波传感技术就卤素离子与铜缓蚀剂——苯骈三氮唑( BTA)协同成膜的动力学及相应复合膜的稳定性进行了研究 .结果表明 ,卤素离子 ( F- ,Cl- ,Br- ,I- )中仅 I- 与 BTA具有协同效应 ,能有效地提高BTA的缓蚀效果和膜层稳定性 ,同时 ,对The growth kinetics and the stability of synergistic films of benzotriazole (BTA) and halide ion (X -) were investigated by bulk acoustic wave (BAW) method.The results show that only I - in halide ions (F -,Cl -,Br -,I -) has synergistic effect with BTA and improves greatly the inhibition efficiency and film stability of BTA in 0.1M H 2SO 4 aqueous solution.Additionally,the film growth behavior of BTA is affected obviously by I - ion.

关 键 词：体声波传感技术 苯骈三氮唑 卤素离子 成膜动力学 协同效应 缓蚀剂 缓蚀效率 

分 类 号：TG174.42[金属学及工艺—金属表面处理]