N-羟基邻苯二甲酰亚胺及其类似物在有机氧化反应中的研究进展  

RESEARCH PROGRESS OF N-HYDROXYPHTHALIMIDE AND ITS ANALOGS IN CATALYTIC OXIDATION

作　　者：张弘[1] 徐保明[1] 张家晖 李俊[1] 陈坤[1] 唐强[1] Zhang Hong;Xu Baoming;Zhang Jiahui;Li Jun;Chen Kun;Tang Qiang(Hubei Province Postgraduate Workstation,Hubei University of Technology,Wuhan 430068,Hubei,China)

机构地区：[1]湖北省研究生工作站,湖北工业大学,湖北武汉430068

出　　处：《精细石油化工》2018年第6期76-80,共5页Speciality Petrochemicals

基　　金：科技部中小企业创业基金(12C26214204453);湖北省教育厅产学研重大项目(CXY2009A010).

摘　　要：综述了以N-羟基邻苯二甲酰亚胺(NHPI)及其类似物构建的催化体系在有机物氧化中的研究应用现状。从反应条件、催化活性及氧化反应机理等方面进行了重点评述,指出通过新官能团引入,分子结构构建等手段制备具备特殊功能的NHPI类似物是今后开发高效NHPI催化氧化体系的重点发展方向之一。The research status of N-hydroxyphthalimide (NHPI)and its analogues of the catalytic systems for the oxidation of organic compounds are introduced.The reaction conditions,catalytic activity and oxidation reaction mechanism of these systems are reviewed.It is pointed out that the preparation of NHPI analogues with special functions through the introduction of new functional groups and the construction of molecular structures will be one of the key development directions for the development of efficient NHPI catalytic oxidation systems in the future.

关 键 词：N-羟基邻苯二甲酰亚胺 有机小分子催化剂 催化氧化 

分 类 号：O643.32[理学—物理化学]