联茚满四酮和二羟基萘并萘二酮异构体的合成与性质  

Synthesis and properties of biindanylidene-1,1',3,3'-tetraone and dihydroxynaphthacene-5,12-dione isomer

作　　者：李旭 周波 李彩云 王永明 杨勤 高洪泽 LI Xu;ZHOU Bo;LI Cai-yun;WANG Yong-ming;YANG Qin;GAO Hong-ze(Basic Subject Application and Development Research Center,Chinese People's Police Academy University, Langfang 065000,China)

机构地区：[1]中国人民警察大学基础学科应用和发展研究中心,河北廊坊065000

出　　处：《化学工程师》2018年第12期6-8,共3页Chemical Engineer

基　　金：国家自然科学基金培育课题(ZKJJPY201707);河北省科技厅计划项目(No.16212303);河北省高等学校科学技术研究项目(Z2017071)

摘　　要：以甲基邻苯二甲酸酐和丁二酸为起始原料,经一系列反应同时得到了5,5'-二甲基-2,2'-联茚满-1,1',3,3'-四酮和3,8-二甲基-6,11-二羟基萘并萘-5,12-二酮两种化合物。研究了它们的结构和性质,结果表明,这两种化合物互为同分异构体,5,5'-二甲基-2,2'-联茚满-1,1',3,3'-四酮能产生稳定的自由基,3,8-二甲基-6,11-二羟基萘并萘-5,12-二酮既能产生稳定自由基又具荧光性。5,5' -dimethyl -2,2' -biindanylidene -1,1',3,3' -tetraone and 3,8' - dimethyl -6,11 -dihydroxynaphthacene- 5,12-dione were synthesized using 4-methylphthalic anhydride and butanedioic acid as the starting materials. The structure and properties of the two compounds were investigated. The results show that, The two compounds are isomers,5,5' -dimethyl -2,2' -biindanylidene -1,1',3,3' -tetraone have paramagnetic. 3,8' -dimethyl - 6,11-dihydroxynaphthacene-5,12-dione can produce stable free radical and fluorescence.

关 键 词：二茚满四酮 萘并萘二酮 顺磁性 荧光 

分 类 号：O621.3[理学—有机化学]