腰果酚改性酚醛泡沫树脂的研究  

Study on Modification of Phenolic Resin Foam With Cardanol

作　　者：李刚[1] 李成吾[1] 左继成[1] 常军[1] LI Gang;LI Cheng-wu;ZUO Ji-cheng;CHANG Jun(Department of Polymer Materials and Engineering,School of Materials Science and Engineefing,Shenyang Ligong University, Liaoning Shenyang 110059,China)

机构地区：[1]沈阳理工大学材料学院高分子材料与工程系,辽宁沈阳110059

出　　处：《辽宁化工》2018年第12期1198-1200,共3页Liaoning Chemical Industry

基　　金：沈阳市科技局国际合作专项目基金(F16-233-6-00)

摘　　要：采用腰果酚作增韧剂对酚醛泡沫树脂进行增韧改性。通过改变反应温度、反应时间、催化剂用量等合成酚醛树脂并制备酚醛泡沫。测定其拉伸强度、固含量、红外光谱图并进行可发泡性试验,最终得到改性酚醛泡沫的最佳工艺条件。实验发现当腰果酚代替量(质量分数)35%,反应温度为100℃,反应时间为3.5 h,催化剂二水合草酸用量为1.65 g时,酚醛树脂的性能最好,拉伸强度为1.8MPa,且发泡效果比较好。The study on toughening modification of phenolic resins with cardanol was carried out.In the experiment,phenol formaldehyde resin was prepared and foamed by changing the reaction temperature,reaction time,catalyst dosage,etc.Tensile strength test,solids content analysis and IR spectra were used.A foaming test of PF resin was carried out in this study.The optimum conditions were determined as follow:the cardanol dosage 35,the reaction temperature 100℃,the reaction time 3.5h,the catalyst dosage 1.65g.The tensile strength of cardanol modified RF resin was 1.8MPa and the foaming property was better.

关 键 词：酚醛树脂 腰果油 正交试验 改性 

分 类 号：TQ323.1[化学工程—合成树脂塑料工业]