微反应器技术在聚合中的应用研究进展  

Research Progress of the Applications of Microreactor Technology in Polymerization

作　　者：袁炜[1] 刘卫卫 李倩[2] 李化毅[2] 胡友良[2] YUAN Wei;LIU Wei-wei;LI Qian;LI Hua-yi;HU You-liang(Research and Development Center of Shenhua Ningxia Coal Industry Group Co.,Ltd,Yinchuan 750411,China;Key Laboratory of Engineering Plastics,Institute of Chemistry,Chinese Academy of Sciences, Beijing 100190,China)

机构地区：[1]神华宁夏煤业集团有限责任公司煤炭化学工业技术研究院,银川750411 [2]中国科学院化学研究所工程塑料重点实验室,北京100190

出　　处：《高分子通报》2019年第1期94-101,共8页Polymer Bulletin

基　　金：国家自然科学基金资助项目(5177030603)

摘　　要：微反应器因其优良的传热、传质性能在聚合反应中的研究方兴未艾。与传统釜式聚合相比,微反应器聚合能够更好地调控聚合物分子量分布,提高聚合反应速率,控制聚合物分子结构和产物形貌。本文综述了微反应器技术在配位聚合、开环聚合和光诱导可控自由基聚合中的研究进展,并简要介绍了微反应器聚合技术的放大实验。最后,对微反应器技术在聚合物合成中的发展方向提出展望。The research of microreactor in the field of polymerization reactions is booming due to its excellent heat and mass transfer performance.Compared with the conventional tank reactor,microreactor technology can regulate the polymer molecular weight distribution and improve the polymerization rate better,as well as control the polymer molecular structures and product morphologies.In this short review,the research progress of microreactor technology in coordination polymerization,ring-opening polymerization and photoinduced controlled radical polymerization are summarized,and the scale-up of the microreactor polymerization technology is briefly introduced.Finally,the development trend of the microreactor technology in polymerization is prospected.

关 键 词：微反应器 聚合反应 配位聚合 开环聚合 光诱导可控自由基聚合 

分 类 号：TQ315[化学工程—高聚物工业]