Synthesis, Structure, and Optical Limiting Properties of an Axial Substituted Bis(8-oxide quinoline)zirconium Phthalocyanine  

作　　者：YOU Ming-Hua FANG Xin LIN Mei-Jin 游名花;方昕;林梅金

机构地区：[1]College of Zhicheng, Fuzhou University [2]College of Chemistry, Fuzhou University

出　　处：《Chinese Journal of Structural Chemistry》2018年第12期1971-1978,1846,共9页结构化学（英文）

基　　金：supported by the Natural Science Foundation of Fujian Province(2018J01431 and 2018J01690);Research Foundation of Education Bureau of Fujian Province(JT180813)

摘　　要：A novel bis(8-oxide quinoline)zironium phthalocyanine [(OQ)2 Zr Pc] with two 8-oxide quinolone anions at the same axial positions has been successfully synthesized and its chemical structure has been assigned by the 1 H NMR, MS and two-dimensional correlation infrared(2D-IR) spectroscopy as well as by single-crystal X-ray structural analysis. It possessed a moderately effective nonlinear absorption coefficient βeff of 6.69×10-14cm/GW at 532 nm in DMF solution, implying it is a promising candidate for nonlinear optical materials.A novel bis(8-oxide quinoline)zironium phthalocyanine [(OQ)2 Zr Pc] with two 8-oxide quinolone anions at the same axial positions has been successfully synthesized and its chemical structure has been assigned by the 1 H NMR, MS and two-dimensional correlation infrared(2D-IR) spectroscopy as well as by single-crystal X-ray structural analysis. It possessed a moderately effective nonlinear absorption coefficient βeff of 6.69×10^(-14) cm/GW at 532 nm in DMF solution, implying it is a promising candidate for nonlinear optical materials.

关 键 词：phthalocyanines zirconium complex axial substitution single-crystal structure optical limiting properties 

分 类 号：TQ[化学工程]